N-(4-Methyl-2-nitrophenyl)succinamic acid
نویسندگان
چکیده
In the title compound, C(11)H(12)N(2)O(5), the conformation of the N-H bond in the amide segment is syn to the ortho-nitro group in the benzene ring. The amide C=O and the carboxyl C=O of the acid segment are syn to each other and both are anti to the H atoms on the adjacent -CH(2) groups. Furthermore, the C=O and O-H bonds of the acid group are in syn positions with respect to each other. The dihedral angle between the benzene ring and the amide group is 36.1 (1)°. The amide H atom shows bifurcated intra-molecular hydrogen bonding with an O atom of the ortho-nitro group and an inter-molecular hydrogen bond with the carbonyl O atom of another mol-ecule. In the crystal, the N-H⋯O(C) hydrogen bonds generate a chain running along the [100] direction. Inversion dimers are formed via a pair of O-H⋯O(C) interactions, that form an eight-membered hydrogen-bonded ring involving the carboxyl group.
منابع مشابه
N-(4-Chloro-3-nitrophenyl)succinamic acid
In the title compound, C(10)H(9)ClN(2)O(5), the nitro group is significantly twisted out of the plane of the benzene ring to which it is attached [dihedral angle = 27.4 (6)°]. In the crystal, mol-ecules are linked into centrosymmetric dimers via pairs of O-H⋯O hydrogen bonds. These dimers are further linked by N-H⋯O hydrogen bonds into double chains running along the a axis.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012